Utilization of Sewage Sludge of Leather Industry. Energy Prospects

Authors

  • О. R. Mokrousova Kyiv National University of Technologies and Design
  • О. A. Okhmat Kyiv National University of Technologies and Design
  • D. V. Mariin Vinnytsia National Technical University
  • A. A. Kulyk Vinnytsia Cooperative Institute;
  • H. V. Sakalova Vinnytsia National Technical University

DOI:

https://doi.org/10.31649/1997-9266-2025-178-1-51-57

Keywords:

leather waste, tannery sludge, biofuels, biogas, biodiesel

Abstract

The growing amount of tannery sludge generated by leather processing often undergoes uncontrolled landfilling, or open dumping, releasing a significant volume of harmful pollutants, including carcinogenic chromium (Cr) into the air, water, and soil. Therefore, sustainable TS management through advanced valorization technologies becomes vital to align with the Sustainable Development Goals (SDGs) and mitigate the adverse environmental, health, and social impacts.

Tannery sludge, as biomass, can be considered a renewable energy source for bioenergy generation which could be a viable solution for meeting contemporary environmental standards and expediting the transition towards a circular economy.

Tannery sludge is an available resource that has been successfully used in anaerobic digestion, biogas, biodiesel, and industrial oil production. We offered a critical review of tannery sludge valorization technologies towards energy recovery.

Many studies have shown that typical anaerobic digestion of tannery sludge requires a long period with low utilization efficiency and biogas yield. Chromium leaching is a major problem in composting and anaerobic digestion of this waste.

Overall, the use of tannery sludge is proving to be a very promising alternative for biodiesel production.

We also explored the environmental hazards of chrome-containing tannery sludge. Tannery sludge valorization is sensitive and critical due to the potential risk of transforming Cr(III) to Cr(VI) during the process. Therefore, there exists an urgent need for considering efficient and holistic tannery sludge valorization technologies in the design, implementation, and operations phases to avoid any environmental and health hazards.

Author Biographies

О. R. Mokrousova, Kyiv National University of Technologies and Design

Dr. Sc. (Eng.), Professor, Head of the Chair of Biotechnology, Leather and Fur, Kyiv National University of Technologies and Design; Professor of the Chair of Commodity Science and Customs Affairs, State University of Trade and Economics

О. A. Okhmat, Kyiv National University of Technologies and Design

Cand. Sc. (Eng.), Associate Professor of the Chair of Biotechnology, Leather and Fur

D. V. Mariin, Vinnytsia National Technical University

Post-Graduate Student of the Chair of Ecology, Chemistry and Environmental Protection Technologies

A. A. Kulyk, Vinnytsia Cooperative Institute;

Head of the Chair of Natural, Legal and Social Sciences

H. V. Sakalova, Vinnytsia National Technical University

Dr. Sc. (Eng.), Professor, Professor of the Chair of Ecology, Chemistry and Environmental Protection Technologies

References

I. Voytovych, M. Malovanyy, V. Zhuk, and O. Mukha, “Facilities and problems of processing organic wastes by family-type biogas plants in Ukraine,” J. Water & Land Develop, vol. 45, no. IV-VI, pp. 499, 185-189. 2020. https://doi.org/10.24425/jwld.2020.133493 .

М. П. Жалдак, В. О. Полюга, і О. Р. Мокроусова, Запровадження принципів сталої біоекономіки у переробці сировини біогенного походження. Зелена трансформація та стала біоекономіка, моногр. Київ: КНУТД, 2024, с. 383-415. ISBN 978-617-7763-34-4.

I. Tymchuk, M. Malovanyy, O. Shkvirko, and K. Yatsukh, “Sewage Sludge as a Component to Create a Substrate for Biological Reclamation,” Ecol. Eng. Environ. Technol., vol. 22, no. 4, pp. 229-237, 2021. https://doi.org/10.12912/27197050/137863 .

O. Savchuk, P. Rebrikova, T. Vovk, N. Raksha, L. Ostapchenko, and O. Mokrousova, “Use of waste from the leather industry for the production of biotechnological products based on collagen,” in IOP Conf. Series: Mater. Scienc. Engin., 2019, no. 500. pp. 012020. https://doi.org/10.1088/1757-899X/500/1/012020 .

Maistrenko L., et al., “Collagen Obtained from Leather Production Waste Provides Suitable Gels for Biomedical Applications,” Polymers, vol. 14, no. 21, pp. 47-49, 2022. https://doi.org/10.3390/polym14214749 .

K. Chojnacka, et al., “Progress in sustainable technologies of leather wastes valorization as solutions for the circular economy,” J. Clean. Prod., no. 313, pp. 127902, 2021. https://doi.org/10.1016/j.jclepro.2021.127902 .

Li Yanchun, Guo Ruijun, Lu Wenhui, and Zhu Deyi, “Research progress on resource utilization of leather solid waste,” Journal of Leather Science and Engineering, vol. 1, no. 6, 2019. https://doi.org/10.1186/s42825-019-0008-6 .

R. Korol, H. Sakalova, “Methanogenesis of waste in technical systems as an energy conservation factor,” Personal. Environ. Is., no. 2, pp. 22-25, 2022. https://doi.org/10.31652/2786-6033-2022-1(2)-22-25 .

G. D. Zupančič, and A. Jemec, “Anaerobic digestion of tannery waste: semi continuous and anaerobic sequencing batch reactor processes,” Bioresour Technol., vol. 101, no. 1, pp. 26-33, 2010. https://doi.org/10.1016/jbiortech200907028 .

Y. Li, S. Y. Park, and J. Zhu, “Solid-state anaerobic digestion for methane production from organic waste,” Renew. Sust. Energ. Rev., vol. 15, no. 1, pp. 821-826, 2010. https://doi.org/10.1016/ jrser201007042 .

C. B. Agustini, J. T. Da Fontoura, B. Mella, and M. Gutterres, “Evaluating co-substrates to supplement biogas production from tannery solid waste treatment – cattle hair, microalgae biomass, and silicone,” Biofuels. Bioprod. Biorefin., vol. 12, no. 6, pp.1095-1102, 2018. https://doi.org/10.1002/bbb.1929 .

N. B. Golub, M. B. Shinkarchuk, A. V. Shynkarchuk, Zh. Y. Xinhua, and O. A. Kozlovets, “Vulnerabilities in the Production of Biogas from the Fat-Containing Tannery Waste,” Innov. Biosyst Bioeng., vol. 3, no. 4, pp. 253-260. 2019. https://doi.org/ 10.20535/ibb201934185425 .

Md. Abdul Moktadir, Ren Jingzheng, and Zhou Jianzhao, “A systematic review on tannery sludge to energy route: Current practices, impacts, strategies, and future directions,” Science of the Total Environment, no. 901, pp.901166244, 2023. https://doi.org/10.1016/j.scitotenv.2023.166244 .

V. Muralidharan, S. Palanivel, and M. Balaraman, “Turning problem into possibility: a comprehensive review on leather solid waste intra-valorization attempts for leather processing,” J. Clean. Prod., no. 367, pp. 133021, 2022. https://doi.org/10.1016/j. jclepro.2022.133021 .

SB. K. Kameswari, C. Kalyanaraman, S. Porselvam, and K. Thanasekaran, “Enhancement of biogas generation by addition of lipase in the co-digestion of tannery solid wastes,” Clean Soil Air Water, no. 20, pp. 10004, 2010. https://doi.org/10.1002/clen20100040 .

M. Yuliana, et al., “A one-pot synthesis of biodiesel from leather tanning waste using supercritical ethanol: process optimization,” Biomass Bioenergy, no. 142, pp.105761, 2020. https://doi.org/10.1016/j.biombioe.2020.105761 .

L. Šánek, J. Pecha, K. Kolomazník, M. Bařinová, “Biodiesel production from tannery fleshings: feedstock pretreatment and process modeling,” Fuel., no.148, pp. 16-24, 2015. https://doi.org/10.1016/j.fuel.2015.01.084 .

V. K. Booramuthy, R. Kasimani, and S. Pandian, “Biodiesel production from tannery waste using a nano catalyst (ferric-manganese doped sulphated zirconia),” Energy Sources, Part A.: Recovery, Utilization, and Environmental Effects, 4 no. 11, pp. 1092-110, 2019. https://doi.org/10.1080/15567036.2019.1639849 .

E. Souza, and L. Silva, “Energy recovery from tannery sludge wastewaters through photocatalytic hydrogen production,” J. Environ. Chem. Eng., no. 4, pp. 2114-2120, 2016. https:// doi.org/10.1016/j.jece.2016.03.040 .

V. Kumar, and I. S. Thakur, “Extraction of lipids and production of biodiesel from secondary tannery sludge by in situ transesterification,” Bioresour. Technol. Rep., no. 11, pp.100446, 2020. https://doi.org/10.1016/j.biteb.2020.100446 .

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Published

2025-02-27

How to Cite

[1]
Mokrousova О. R., Okhmat О. A., D. V. Mariin, A. A. Kulyk, and H. V. Sakalova, “Utilization of Sewage Sludge of Leather Industry. Energy Prospects”, Вісник ВПІ, no. 1, pp. 51–57, Feb. 2025.

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ECOLOGY AND ENVIRONMENTAL SECURITY

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